| 1. | Prime Minister and Union Minister at the Prime Minister’s Office and Union Minister for National Planning | U Nyo Saw |
| 2. | Union Minister Ministry (1) of the President’s Office | U Tin Aung San |
| 3. | Union Minister Ministry (2) of the President’s Office | U Ko Ko Hlaing |
| 4. | Union Minister Ministry (3) of the President’s Office | U Maung Maung Tint |
| 5. | Union Minister Ministry (4) of the President’s Office | U Tun Ohn |
| 6. | Union Minister Ministry of Transport and Communications | U Mya Tun Oo |
| 7. | Union Minister Ministry of Defence | General Maung Maung Aye |
| 8. | Union Minister Ministry of Home Affairs | Lt-Gen Tun Tun Naung |
| 9. | Union Minister Ministry of Foreign Affairs | U Than Swe |
| 10. | Union Minister Ministry of Finance and Revenue | Dr Kan Zaw |
| 11. | Union Minister Ministry of Border Affairs and Ethnic Affairs | Lt-Gen Yar Pyae |
| 12. | Union Minister Ministry of Investment and Foreign Economic Relations | Dr Wah Wah Maung |
| 13. | Union Minister Union Minister and Attorney-General of the Union Ministry of Legal Affairs | Dr Thida Oo |
| 14. | Union Minister Ministry of Information | U Maung Maung Ohn |
| 15. | Union Minister Ministry of Religious Affairs and Culture | U Tin Oo Lwin |
| 16. | Union Minister Ministry of Agriculture, Livestock and Irrigation | U Min Naung |
| 17. | Union Minister Ministry of Cooperatives and Rural Development | U Hla Moe |
| 18. | Union Minister Ministry of Natural Resources and Environmental Conservation | U Khin Maung Yi |
| 19. | Union Minister Ministry of Electric Power | U Nyan Tun |
| 20. | Union Minister Ministry of Energy | U Ko Ko Lwin |
| 21. | Union Minister Ministry of Industry | Dr Charlie Than |
| 22. | Union Minister Ministry of Immigration and Population | U Myint Kyaing |
| 23. | Union Minister Ministry of Labour | U Aung Kyaw Hoe |
| 24. | Union Minister Ministry of Commerce | U Chit Swe |
| 25. | Union Minister Ministry of Education | Dr Chaw Chaw Sein |
| 26. | Union Minister Ministry of Science and Technology | Dr Myo Thein Kyaw |
| 27. | Union Minister Ministry of Health | Dr Thet Khaing Win |
| 28. | Union Minister Ministry of Sports and Youth Affairs and Ministry of Hotels and Tourism | Jeng Phang Naw Taung |
| 29. | Union Minister Ministry of Construction | U Myo Thant |
| 30. | Union Minister Ministry of Social Welfare, Relief and Resettlement | Dr Soe Win |
| 31. | Director-General Union Government’s Office | U Nay Lin |